| PATENT NUMBER | This data is not available for free |
| PATENT GRANT DATE | January 23, 1996 |
| PATENT TITLE |
Silicone polymers for the modification of zinc oxide |
| PATENT ABSTRACT | A silicone composition and process for hydrophobizing zinc oxide, and the resultant hydrophobic zinc oxide are disclosed. The silicone composition is a reactive alkoxy silicone which is applied to the zinc oxide then in a subsequent step the coated zinc oxide is heated to 40.degree. to 100.degree. C for between 1 and 10 hours for the reaction to occur. The resulting zinc oxide is hydrophobic, non-reactive, and not affected by water |
| PATENT INVENTORS | This data is not available for free |
| PATENT ASSIGNEE | This data is not available for free |
| PATENT FILE DATE | June 14, 1995 |
| PATENT CLAIMS |
We claim: 1. A hydrophobic zinc oxide which is prepared by the reaction of a silicone compound conforming to the following structure: ##STR8## Me is methyl; R is alkyl having one to ten carbon atoms; R' is methyl or ethyl; a is an integer ranging from 4 to 12; with zinc oxide. 2. A hydrophobic zinc oxide of claim 1 wherein the concentration of silicone compound ranges from 0.1 to 25% by weight. 3. A hydrophobic zinc oxide of claim 1 wherein the concentration of silicone compound ranges from 0.5 to 20% by weight. 4. A hydrophobic zinc oxide of claim 1 wherein the concentration of silicone compound ranges from 1.0 to 10% by weight. 5. A hydrophobic zinc oxide of claim 1 wherein a is an integer ranging from 6 to 12. 6. A hydrophobic zinc oxide of claim 1 wherein a is an integer ranging from 4 to 8. 7. A hydrophobic zinc oxide of claim 1 wherein R is methyl. 8. A hydrophobic zinc oxide of claim 1 wherein R is octyl. 9. A hydrophobic zinc oxide of claim 1 wherein R is butyl. 10. A process for hydrophobizing zinc oxide which comprises: contacting zinc oxide with an effective hydrophobizing concentration of a silicone which conforms to the following structure: ##STR9## Me is methyl; R is alkyl having one to ten carbon atoms; R' is methyl or ethyl; a is an integer ranging from 4 to 12; then heating the mixture to a temperature of between 40.degree. C. and 100.degree. C., for two to ten hours. 11. A process of claim 10 wherein the effective hydrophobizing concentration of silicone compound ranges from 0.1 to 25% by weight. 12. A process of claim 10 wherein the effective hydrophobizing concentration of silicone compound ranges from 0.5 to 20% by weight. 13. A process of claim 10 wherein the effective hydrophobizing concentration of silicone compound ranges from 1.0 to 10% by weight. 14. A process of claim 10 wherein a is an integer ranging from 6 to 12. 15. A process of claim 10 wherein a is an integer ranging from 4 to 8. 16. A process of claim 1 wherein R is methyl. 17. A process of claim 10 wherein R is octyl. 18. A process of claim 1 wherein R is butyl. |
| PATENT DESCRIPTION |
This invention relates a silicone composition, a process for the hydrophobization of zinc oxide and the resultant hydrophobized zinc oxide. Compositions made according to the invention are very effective as delivery systems which produce uniform hydrophobic film which are not interrupted by extraneous oils, water and other additives which may be in the final formulated product. The zinc oxide modified by this process results in a more chemically inert particle. DESCRIPTION OF THE ART Zinc oxide is a well known material useful in a variety of applications. It is used as a pigment in paint, as an additive in cosmetic products, cements, glass, rubber, glue, matches, inks and semiconductors. The use of zinc oxide in so many applications areas is a direct result of the many differing properties of the pigment. Zinc oxide is a reactive material which exhibits a wide range of reactivity with alkaline as well as acidic solutions, liquids and gases. In some applications the reactive nature of the zinc oxide is desirable, for example in paint applications, the reactivity of the pigment results in adhesion into the polymer film. In many applications, it is highly desirable to have zinc oxide in a non-reactive form, that is to eliminate, or make unavailable, the active sites present on the molecule. Harvey Brown in his book Zinc Oxide Properties and Applications (International Lead Zinc Research Organization) states zinc oxide displays a high degree of reactivity in water with a wide range of materials, including acids, acid salts, and alkaline materials. Many of the resulting compounds are complex structures because of the variety of species furnished by zinc oxide in aqueous solution. Brown goes on to state that zinc oxychloride, zinc phosphates, zinc silicates, and a variety of other materials can be formed in aqueous media. One measure of the availability of reactive groups on the zinc oxide is pH change associated with use of zinc oxide. Zinc oxide containing reactive sites can increase the pH of aqueous products. In some instances the increase can be from an initial pH of 7 to a pH of 8.7. This increase is not only a measure of the presence of reactive groups, but is highly undesirable in the formulation. It is therefore very desirable to produce a zinc oxide which has the pigment properties but lacks the reactivity found in untreated zinc oxide. One area in which zinc oxide has been used is in sun screen products. It protects the skin from sun. The traditional materials used for protecting the skin from the harmful effect of the sun are the organic sun screens. These include para amino benzoic acid and other materials which absorb ultra violet light. Recently, studies have indicated that ultra violet light is a major factor in the ageing of skin. This has resulted in the incorporation of sun screens in products which are not aimed specifically for use at the beach, like make up. Additionally, there has been an increased interest in providing higher levels of protection to the skin. The so called SPF system has been developed to evaluate various materials for their effectiveness in protecting the skin from the damaging affects of the sun. The quest for higher and higher SPF values has resulted in the use of greater levels of organic sun screen. These materials have a tendency to be irritating at high concentrations, and have the affect of increasing the available organic material for bacteria. This results in the need for more preservative to protect the higher level of organic sun screen agent from bacterial degradation. The higher levels of preservative result in higher irritation levels, which can be addressed by incorporation of irritation mitigants, which themselves are degraded by bacteria. The use of inorganic sun screen agents like zinc oxide is a good way around the use of organic sun screens, since they are not attacked by bacteria. However, their use does have some other inherent problems. Specifically, these materials are not easily formulated into stable products, due to the reactivity issues raised above. Zinc oxide tends to agglomerate in many finished formulations, loosing it's effectiveness in the formulation and resulting in unacceptable aesthetic results, most commonly whitening and viscosity changes. Additionally, zinc oxide tends to raise the pH of the formulation to about 8.5 which is too high for many skin care formulations. These formulations tend to be useful at a pH of 6-7. Zinc oxide has limited usefulness as is due to these problems. One approach has been to pre-disperse the zinc oxide in an organic oil like Siltech's patented tri-(octyldodecyl)citrate. While the dispersion is fairly stable, the coating is not permanent since there is no reaction between the oil and the zinc oxide. The oil also disrupts the uniformity of the zinc oxide on the skin. Traditionally, dispersing aids have been added to formulations to minimize the disruptive effect upon the film. These include phosphate esters, and lecithin. These too suffer from the labile nature of the surface treatment and dissociation between the particle and the oil. This is especially evident when zinc oxide is exposed to extreme mechanical or thermal stress as in the production of plastics or stick cosmetics. The present invention overcomes the shortfalls of zinc oxide by reacting a specific silicone compound under controlled conditions to produce a stable, surface treated zinc oxide which maintains it's state of dispersion and does not contribute significantly to chemical instability in the formulation. SUMMARY OF THE INVENTION The present invention discloses (a) a process for hydrophobizing the surface of zinc oxide with a specific type of reactive silicone, and (b) a novel hydrophobic zinc oxide composition. DETAILED DESCRIPTION OF THE INVENTION It has been found that highly effective system for hydrophobizing zinc oxide makes use of a silicone compound conforming to the following structure: ##STR1## Me is methyl; R is alkyl having one to ten carbon atoms; R' is methyl or ethyl; a is an integer ranging from 4 to 12. We have surprisingly learned that the value of "a" is critical in developing a product which gives the desired hydrophobicity. The critical range is from 4 to 12. Zinc oxide's value as a pigment is based upon it's ability to remain dispersed and unreacted. Untreated zinc oxide, placed into water, loses its effectiveness and good aesthetic qualities due to agglomeration. If the value of "a" is too low, the treated zinc oxide is not sufficiently hydrophobic and it's value as a pigment is destroyed. Making zinc oxide permanently hydrophobic by treatment with the correct silicone compound is highly desirable and heretofore very difficult to attain. The compounds of the present invention are hydrophobic zinc oxide which is prepared by the reaction of a silicone compound conforming to the following structure: ##STR2## Me is methyl; R is alkyl having one to ten carbon atoms; R' is methyl or ethyl; a is an integer ranging from 4 to 12; reacted with zinc oxide. The zinc hydrophobizing process comprises; contacting zinc oxide with an effective hydrophobizing concentration of a silicone which conforms to the following structure: ##STR3## Me is methyl; R is alkyl having one to ten carbon atoms; R' is methyl or ethyl; a is an integer ranging from 4 to 12; then heating the mixture to a temperature of between 40.degree. C. and 100.degree. C., for two to ten hours. The product so produced surprisingly is hydrophobic and maintains the desirable performance characteristics making the zinc oxide useful in many applications including as a sun screen. While not wishing to be limited to a specific theory of why only specific silicone compounds of the present invention are effective, we believe that the placement of the reactive groups on the molecule have a dramatic affect upon the efficiency of hydrophobization. The reaction by which hydrophobization occurs is one in which active sites on the zinc oxide reacts with the silicone to result in a covalent bond between silicone and zinc oxide, and the formation of R'OH. The reaction is summarized as follows: ##STR4## It should be clear from the above that the presence of three R' groups on the silicone compound can result in the formation of a multiple bonds bond between silicone the zinc oxide crystals. Since no water is present in this process, the zinc oxide crystals remain intact and "frozen" in shape by the silicone which acts like a matrix for the zinc oxide crystals. The silicone preserves the structure of the zinc oxide crystals, eliminates the reactivity in water, and makes them hydrophobic. This allows for the exposure of the hydrophobic zinc oxide to water without deleterious affect to the zinc oxide or pH drift caused by the reactivity of the zinc oxide in aqueous products. All these improvements are a direct unexpected result of modifying the surface of the zinc oxide with a specific silicone compound, freezing the structure of the zinc oxide, hydrophobizing it and removing the undesired reactivity. When drawn out in it's full structure, it becomes clear that the position of the R' groups can be varied by variation in "a". That is as "a" increases the distance between the R' groups increase and the three dimensional structure changes. ##STR5## We have learned that the value of "a" is critical to the functionality of the hydrophobizing process. Specifically, "a" is zero, the treated zinc oxide does not maintain it's structure when exposed to water. There is little affect upon the effectiveness of the hydrophibization until a value of about 4 is reached. The best performance is attained as a approaches 8. As "a" is increased further the silicone molecule becomes more hydrophobic and higher in molecular weight, this limits it's effectiveness in coating the zinc oxide. In effect the reactive silicone is acting more like an oil than like a hydrophobizing agent, resulting in a zinc oxide which is not covalently bonded to silicone. A non covalent bond is easily removed by contact with water, resulting in agglomeration of the zinc oxide, an elevation of the pH of the formulation, due to reactive groups present in the zinc oxide, and silicone oil floating on the top of the aqueous formulation. The production of R'OH as a by product in a dry process, as opposed to s slurry process, is very desirable. Another approach is the use of silicone compounds containing silanic hydrogen compounds of the structure Si--H, results in the evolution of copious amounts of flammable hydrogen gas. In addition the use of these kinds of compounds do not give the desired properties. PREFERRED EMBODIMENTS In a preferred embodiment the concentration of silicone compound ranges from 0.1 to 25% by weight. In another preferred embodiment the concentration of silicone ranges from 0.5 to 20% by weight. In another preferred embodiment the concentration of silicone ranges from 1.0 to 10.0%. In a preferred embodiment a is an integer ranging from 6 to 12. In another preferred embodiment a is an integer ranging from 4 to 8. In a preferred embodiment R is methyl. In another preferred embodiment R is octyl. In another preferred embodiment R is butyl. In another preferred embodiment R is ethyl. In a preferred embodiment, the process of the present invention is conducted at a temperature of between 80.degree. and 100.degree. C. In another preferred embodiment, the process of the present invention is conducted at a temperature of between 90.degree. and 100.degree. C. |
| PATENT EXAMPLES | available on request |
| PATENT PHOTOCOPY | available on request |
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