| PATENT NUMBER | This data is not available for free |
| PATENT GRANT DATE | April 2, 2002 |
| PATENT TITLE |
Propylene/ethylene random copolymer, molding material, and molded article |
| PATENT ABSTRACT |
The present invention provides propylene/ethylene random copolymers characterized in that: an ethylene content (Ew) is 0.1-10 wt %, a relationship between an isolated ethylene content (E.sub.1) and the ethylene content (Ew) is represented by the following equation E.sub.1 >0.85-0.01 Ew 2,1- and 1,3-propylene units present in a polymer chain are 0-1 mol %, a weight average molecular weight (Mw) is in the range of 40,000-1,000,000, and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to a number average molecular weight(Mn) is in the range of 1.5-3.8. The copolymers are suitable for a base resin for a molding material for the production of a wide variety of molded articles which are high in randomness and excellent in stiffness, heat resistance and transparency. |
| PATENT INVENTORS | This data is not available for free |
| PATENT ASSIGNEE | This data is not available for free |
| PATENT FILE DATE | February 15, 2000 |
| PATENT CT FILE DATE | August 13, 1998 |
| PATENT CT NUMBER | This data is not available for free |
| PATENT CT PUB NUMBER | This data is not available for free |
| PATENT CT PUB DATE | February 25, 1999 |
| PATENT FOREIGN APPLICATION PRIORITY DATA | This data is not available for free |
| PATENT REFERENCES CITED |
"Carbon-13 Nuclear Magnetic Resonance Determination of Monomer Composition and Sequence Distributions in Ethylene-Propylene Copolymers Prepared with a Stereoregular Catalyst System", G. J. Ray et al., Ethylene-Propylene Copolymers, vol. 10, No. 4, Jul.-Aug. 1977, pp. 773-778. "Monomer Sequence Distribution in Ethylene Propylene Elastomers. I. Measurement by Carbon-13 Nuclear Magnetic Resonance Spectroscopy", C. J. Carman et al., Rubber Chem. Technol., 44, (1971), pp. 781-804. "Propylene homo- and copolymerization with ethylene using an ethylenebis(1-indenyl)zirconium dichloride and methylaluminoxane catalyst system", T. Tsutsui et al., Polymer, vol. 30, Jul. 1989, pp. 1350-1356. Ray et al., Macromolecules, vol. 10, No. 4, 773-778, (1977).* European Search Report |
| PATENT CLAIMS |
What is claimed is: 1. A propylene/ethylene random copolymer, wherein: an ethylene content (Ew) is 0.1-10 wt %, a relationship between an isolated ethylene content (E.sub.1) and the ethylene content (Ew) is represented by the following equation: E.sub.1 >0.85-0.01Ew 2,1- and 1,3-propylene units present in the polymer chain are 0-1 mol %, a weight average molecular weight (Mw) is in the range of 40,000-1,000,000, and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to a number average molecular weight (Mn) is in the range of 1.5-3.8. 2. The copolymer of claim 1 wherein the copolymer has the melting point (Tm) in the range of 100-160.degree. C. 3. The copolymer of claim 1 wherein the copolymer is produced by copolymerizing propylene and ethylene in the presence of a supported metallocene catalyst which comprises a transition metal compound and an aluminoxane or a reaction product thereof supported on a fine particle support, and an organoaluminum compound, and further the transition metal compound is represented by the following formula ##STR4## wherein M represents a transition metal selected from the group consisting of titanium, zirconium and hafnium; X and Y may be the same or different and each represents a hydrogen, a halogen or a hydrocarbyl radical; (C.sub.5 H.sub.4-m R.sup.1.sub.m) and (C.sub.5 H.sub.4-n R.sup.2.sub.n) represent a substituted cyclopentadienyl group in which m and n are an integer of 1-3; R.sup.1 and R.sup.2 may be the same or different and each represents a hydrocarbyl radical of 1 to 20 carbons or a silicone-containing hydrocarbyl radical, with the proviso that the position of R.sup.1 and R.sup.2 on the cyclopentadienyl ring gives a configuration wherein any symmetry plane containing M each other is absent; and Q is a divalent hydrocarbyl radical, an unsubstituted silylene group and a hydrocarbyl-substituted silylene group. 4. The copolymer of claim 3 wherein at least one of the substituents R.sup.1 and R.sup.2 in the transition metal compound is attached to a carbon adjacent to the carbon attached to Q in the cyclopentadienyl ring. 5. The copolymer of claim 3 wherein the transition metal compound is dimethylsilylene(2,3,5-trimethylcyclopentadienyl)(2',4',5'-trimethylcyclop entadienyl)zirconium dichloride. 6. The copolymer of claim 3 wherein the supported metallocene catalyst has been pre-activated by preliminary polymerization with small amounts of olefins. 7. A propylene composition comprising the propylene/ethylene random copolymer of claim 1 and a desired additive component. 8. A propylene composition comprising the propylene/ethylene random copolymer of claim 1, an .alpha.-crystal nucleating agent in an amount of 0.0001-1 part by weight based on 100 parts by weight of the copolymer and a desired additive component. 9. A propylene composition comprising the propylene/ethylene random copolymer of claim 1, a radical generator in an amount of 0.001-0.5 part by weight based on 100 parts by weight of the copolymer and a desired additive component. 10. A propylene composition of claim 9 wherein the radical generator is 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, 2,5-dimethyl-2,5-di(t-butylperoxy)hexyne-3, 1,3-bis(t-butylperoxyisopropyl) benzene or a mixture thereof. 11. A propylene composition modified by melt-kneading the composition of claim 9 at a temperature of 150-300.degree. C. 12. A molded article formed from the propylene composition of claim 7. 13. A film formed from the propylene composition of claim 7. 14. A composite polypropylene film comprising a film layer formed from the propylene composition of claim 7 and other polypropylene film layer. 15. A stretched, multi-layer polypropylene film having a heat-seal layer comprising a film layer formed from the propylene composition of claim 7 on at least one surface of a base layer comprising a film containing a crystalline polypropylene as a main component. 16. The multi-layer polypropylene film of claim 15 wherein the crystalline polypropylene has not less than 75% of an isotactic index (I.I.). 17. The multi-layer polypropylene film of claim 15 wherein the crystalline polypropylene has a melt flow rate (MFR) of 0.1-10 g/10 min. 18. The multi-layer polypropylene film of claim 15 which is biaxially oriented. 19. An injection-molded article formed from the propylene composition of claim 7. 20. An injection-molded article formed from the propylene/ethylene random copolymer composition of claim 8. -------------------------------------------------------------------------------- |
| PATENT DESCRIPTION |
FIELD OF THE INVENTION This invention relates to new propylene/ethylene random copolymers with very high randomness. More particularly, the invention relates to propylene/ethylene random copolymers which are suitable as materials for the production of molded articles excellent in stiffness, heat resistance, transparency, etc. BACKGROUND ART Olefin polymers represented by polypropylene and polyethylene have been extensively used as a base resin in the field of various moldings, because of their good mechanical properties, good chemical resistance and very useful balance with economy. These olefin copolymers have been produced by polymerizing olefins using Ziegler-Natta catalyst system comprising a transition metal catalyst component having titanium trichloride, titanium tetrachloride or the mixture thereof supported on a support such as magnesium chloride, in combination with an organoaluminum compound. In recent years, various processes of polymerizing olefins have been proposed using a metallocene catalyst system comprising an organic transition metal compound having specified organic radical different from an inorganic transition metal compound, what is called a metallocene compound in combination with an aluminoxane. The olefin copolymers produced using the metallocene catalyst system are generally those having narrow molecular weight distribution. In particular, where two or more olefins are copolymerized, comonomers are dispersed homogenously and copolymerized, thus producing more homogenous copolymers with high randomness as compared with those using Ziegler-Natta catalyst system. Further, choice of metallocene species can produce an isotactic polypropylene having high stereoregularity. These propylene/ethylene random copolymers are compounded with various additives to form pellets and provided for the manufacture of various molded articles such as films, injection moldings, blow moldings, sheets, fibers, etc. For these molding materials, basic properties of propylene/ethylene copolymers are specified and the additives are selected in accordance with the intended object. EP 0629631, JPA 7-149833 and JPA 8-73532 disclose the application to films of isotactic polypropylenes produced using a metallocene catalyst system. JPA 7-149833 and JPA 8-73532 disclose that propylene/ethylene random copolymers produced by copolymerizing propylene and ethylene using a metallocene catalyst system comprising a particular chiral metallocene compound are characterized by .sup.13 C-NMR spectroscopy and that propylene/ethylene random copolymers having the following characteristics exhibit a heat-sealing property which is one of performances required for film. JPA-7-149833 JPA-8-73532 Ethylene unit content (mol %) 5-50 0.5-5 Triadocticity of propylene unit (%) .gtoreq.90 .gtoreq.95 2,1- and 1,3-propylene units (%) 0.05-0.5 0.05-0.5 Intrinsic viscosity (dl/g) 0.1-12 0.1-12 Melt flow rate (g/10 min) .ltoreq.20 .ltoreq.20 However, these publications give no reference to the randomness of the ethylene unit present in the polymer chain. As one embodiment of polypropylene films, there are biaxially oriented multi-layer films produced generally by laminating a basic layer comprising a crystalline polypropylene film and a heat-seal layer being heat sealable at lower temperature, followed by biaxial orientation. JPA 8-238729 discloses a composite film using as a heat seal layer a propylene/1-butene random copolymer produced with a metallocene catalyst system. This copolymer has 1.0 to 1.5 of parameter B value indicating the randomness in chain distribution of comonomers in the polymer chain. Parameter B value indicating the randomness is represented by the following equation. B=P.sub.12 /(2P.sub.1.multidot.P.sub.2) wherein P.sub.1 and P.sub.2 represent a first monomer content fraction and a second monomer content fraction, respectively, and P.sub.12 represents the proportion of (first monomer)--(second monomer) chain in the whole two molecule chains. JPA 9-110934 (Japanese Patent Appln. 7-272428) filed by the present applicant discloses propylene/ethylene random copolymers produced by copolymerizing propylene and ethylene using an olefin polymerization catalyst comprising a single mixture system of a specific chiral metallocene compound and aluminoxane, and injection moldings and films comprising these copolymers as a base resin. JPA-5-9225, JPA-5-9226 and JPA-5-32723 disclose polypropylene resins produced with the intention of improving the mechanical properties such as stiffness and heat resistance of moldings. These polypropylene resins contain propylene polymers having the temperature (T max) of above 117.0.degree. C. or 118.0.degree. C., which indicates a position of the main elution peak by a temperature fractionation method, and also contain a nucleating agent as a desired component. JPA 7-10932 also discloses a polypropylene resin composition for injection molding which comprises a propylene polymer as a base resin into which a nucleating agent is incorporated. In this propylene polymer, the weight percent of the amount of the propylene polymer dissolved in o-dichlorobenzene between 120.degree. C. and 135.degree. C., based on the total weight of the propylene polymer is more than the value calculated from the equation: (40-15 logMFR).times.100 wherein MFR represents a melt flow rate of propylene polymer. WO 94/28219 discloses a composition for the formation of fibers wherein a low-melting homopolypropylene produced using a metallocene catalyst system is kneaded with a radical generating agent to lower a molecular weight of propylene. As discussed above, different characteristics are required for propylene polymers, depending on the object of molding. Producing separately propylene polymers satisfying such respective characteristics complicates process step and process control, thus increasing the cost of production. OBJECT OF THE INVENTION An object of the invention is to provide a propylene/ethylene random copolymer which is suitable as a base resin for molding materials applicable to a wide variety of molding fields. Another object of the invention is to provide a molding material comprising a propylene/ethylene random copolymer as a main component, which is usable in a wide variety of molding fields. A further object of the invention is to provide a biaxially oriented multi-layer polypropylene film with high transparency, which comprises a polypropylene film having excellent heat resistance and stiffness and very high transparency, and a heat-seal layer having excellent heat-sealing and anti-blocking properties. DISCLOSURE OF THE INVENTION A propylene/ethylene random copolymer of the present invention is characterized in that: an ethylene content (Ew) is 0.1-10 wt %, a relationship between an isolated ethylene content (E.sub.1) and the ethylene content (Ew) is represented by the following equation: E.sub.1 >0.85-0.01Ew 2,1- and 1,3-propylene units present in a polymer chain are 0-1 mol %, a weight average molecular weight (Mw) is in the range of 40,000-1,000,000, and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to a number average molecular weight (Mn) is in the range of 1.5-3.8. The propylene/ethylene random copolymer can be produced by copolymerizing propylene and ethylene in the presence of a supported metallocene catalyst comprising a transition metal compound and aluminoxane or the reaction product thereof supported on a fine particle support and an organoaluminum compound. The above-mentioned transition metal compound is represented by the following formula ##STR1## wherein M represents a transition metal selected from the group consisting of titanium, zirconium and hafnium; X and Y may be the same or different and each represents a hydrogen, a halogen or a hydrocarbyl radical; (C.sub.5 H.sub.4-m R.sup.1.sub.m) and (C.sub.5 H.sub.4-n R.sup.2.sub.n) represent a substituted cyclopentadienyl group in which m and n are an integer of 1-3; R.sup.1 and R.sup.2 may be the same or different and each represents a hydrocarbyl radical of 1 to 20 carbons or a silicone-containing hydrocarbyl radical, with the position of R.sup.1 and R.sup.2 on the cyclopentadienyl ring giving a configuration wherein any symmetry plane containing M each other is absent; and Q is a divalent hydrocarbyl radical, an unsubstituted silylene group and a hydrocarbyl-substituted silylene group. Preferably, at least one of R.sup.1 and R.sup.2 substitutes a carbon adjacent to a carbon attached to Q in the cyclopentadienyl ring. The first embodiment of molding materials according to the present invention is a propylene composition comprising the propylene/ethylene random copolymer and a desired additive component. The second embodiment of molding materials is a propylene/ethylene random copolymer composition comprising an .alpha.-crystal nucleating agent in an amount of 0.0001-1 part by weight based on 100 parts by weight of the copolymer and a desired additive component. The third embodiment of molding materials is a propylene/ethylene random copolymer composition comprising the propylene/ethylene random copolymer, a radical generator in an amount of 0.001-0.5 part by weight based on 100 parts by weight of the copolymer and a desired additive component. This composition is modified by melt kneading of the above individual components at a temperature of 150 to 300.degree. C. The molded articles according to the present invention include films, sheets, injection moldings, extrusion moldings, blow moldings and fibers which are formed from the above first molding materials, the propylene compositions. The films according to the present invention are those formed from the above first molding materials, the propylene compositions. Another embodiment of the films according to the present invention is a composite film comprising a film layer formed from the above first molding materials, the propylene compositions and other polypropylene films. A further embodiment of the films according to the present invention is a stretched, multi-layer polypropylene film having a heat-seal layer comprising a film layer formed from the above first molding materials on at least one surface of the basic layer comprising a crystalline polypropylene as a main component. This multi-layer polypropylene film is preferably biaxially oriented. The first embodiment of the molded articles according to the present invention is injection moldings molded from the above first molding materials, the propylene compositions. The second embodiment of the molded articles is injection moldings molded from the above second molding materials, the propylene/ethylene random copolymer compositions. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is .sup.13 C NMR spectrum of the propylene/ethylene random copolymer produced in Example 1. FIG. 2 is .sup.13 C NMR spectrum of the propylene/ethylene random copolymer produced in Example 2. FIG. 3 is .sup.13 C NMR spectrum of the propylene/ethylene random copolymer produced in Comparative Example 2. FIG. 4 is a flow sheet of the process for the production of the propylene/ethylene random copolymer according to the present invention. DETAILED DESCRIPTION OF THE INVENTION The propylene/ethylene random copolymer of the present invention has the following characteristics. (i) The ethylene content (Ew) determined by .sup.13 C-NMR spectroscopy is 0.1-10 wt % (0.15-16.67 mol %). (ii) The relationship between an isolated ethylene content (E.sub.1) determined by .sup.13 C-NMR spectroscopy and the ethylene content (Ew) is represented by the following equation. E.sub.1 >0.85-0.01Ew (iii) The 2,1- and 1,3-propylene units present in a polymer chain determined by .sup.13 C-NMR spectroscopy are 0-1 mol %. (iv) The weight average molecular weight (Mw) determined by GPC is in the range of 40,000-1,000,000. (v) The ratio (Mw/Mn) of the weight average molecular weight (Mw) to a number average molecular weight (Mn) determined by GPC is in the range of 1.5-3.8. In addition, (vi) A melt flow rate (MFR) determined in accordance with JIS K 7210 is 1 g/10 min or more, preferably 20 g/10 min or more. (vii) A melting point (Tm) determined by differential scanning calorimetric analyzer is in the range of 100 to 160.degree. C. The characteristics of the propylene/ethylene random copolymers by .sup.13 C-NMR spectroscopy can be calculated from .sup.13 C-NMR spectra which were determined for a solution of 20% by weight of the polymer in a mixed solvent of o-dichlorobenzene/benzene bromide with 8/2 weight ratio under the condition of 67.20 MHz and 130.degree. C., using a NMR spectrometer (e.g., JEOL-GX270 manufactured by Nihon Densi K. K. in Japan). (i) The ethylene content (Ew) can be calculated from the following equation proposed by G. Joseph Ray et al. in Macromolecules, 10, 773 (1977), the assignment of each peak in .sup.13 C-NMR spectra being calculated in accordance with the assignment method outlined by Carman et al. in Rubber Chem. Technol., 44, 781 (1971), Ew=[28.0521Ie/(28.052Ie+42.078Ip)].times.100(wt %) wherein Ie represents a total integral value of all peaks due to the ethylene unit and Ip represents a total integral value of all peaks due to the propylene unit. The ethylene content (EW) of the propylene/ethylene random copolymer according to the present invention is in the range of 0.1-10 wt %, preferably 0.1-5 wt %. Excessive ethylene content will result in lowering the crystallinity of the propylene/ethylene random copolymer, thus lowering the heat resistance of the molded articles comprising said copolymer as a base resin. (ii) The isolated ethylene content (E.sub.1) can be calculated from the following equation proposed by G. Joseph Ray et al. in the above reference, the assignment of each peak in .sup.13 C-NMR spectra being calculated in accordance with the assignment method by Carman et al. as mentioned above, E.sub.1 =0.5.times.(0.5I.sub..alpha..gamma. +I.sub..beta..beta.)/Ie wherein I.sub..alpha..gamma. and I.sub..beta..beta. represent a total integral value of peaks for which each is assigned and Ie represents the same meaning as mentioned above. That is, the isolated ethylene content is the proportion of the ethylene unit present in the sequence of propylene-ethylene-propylene (PEP), based on the total ethylene units present in the polymer chain. The sequence of the ethylene unit present in three successive monomers may be EPP (ethylene-propylene-propylene), PPE (propylene-propylene-ethylene), EEP (ethylene-ethylene-propylene), EPE (ethylene-propylene-ethylene), PEE (propylene-ethylene-ethylene) and EEE (ethylene-ethylene-ethylene), in addition to the above PEP. The ethylene unit present in the sequence of PEP represents a true isolation, i.e., the randomness of the propylene/ethylene random copolymer. The higher E.sub.1 value indicates the higher randomness. The relationship between the isolated ethylene content (E.sub.1) and the ethylene content (Ew) is represented by the following equation: E.sub.1 >0.85-0.01Ew The above equation shows that not less than 75% of the ethylene unit present in the polymer chain of the propylene/ethylene random copolymer according to the present invention is present as the isolated ethylene, i.e., in the sequence of PEP, even if the ethylene content (Ew) is 10 wt %. The isolated ethylene content (E.sub.1) of the propylene/ethylene random copolymer, i.e., randomness has an effect on the mechanical properties of the molded articles comprising said copolymer as a base resin, and particularly has a great effect on the transparency. Higher randomness gives molded articles having excellent transparency. (iii) In the propylene/ethylene random copolymer, the 2,1- and 1,3-propylene units in the polymer chain can be calculated from .sup.13 C NMR spectra based on the method proposed by T. Tsutsui et al. in POLYMER, Vol. 30, 1350 (1989). It is known by POLYMER, Vol. 30, 1350 (1989) that in the copolymerization of propylene and ethylene using a Ziegler-Natta catalyst system, the polymerization reaction proceeds in such a manner that most of the propylene unit in the polymer chain is in the form of 1,2-insertion, whereas in the copolymerization of propylene and ethylene using a metallocene catalyst system, a 1,2-insertion reaction may be predominant for the propylene unit, simultaneously with the 2,1- and 1,3-insertion reactions, with the result that irregular 2,1- and 1,3-propylene units in the polymer chain lower the melting point of the propylene/ethylene random copolymer. In the propylene/ethylene random copolymer of the present invention, the 2,1- and 1,3-propylene units in the polymer chain are in the range of 0 to 1 mol %, preferably 0.1 to 0.7 mol %, and more preferably 0.2 to 0.5 mol %. The 2,1- and 1,3-propylene units in the polymer chain influence the melting point of the propylene/ethylene random copolymer and have an effect on the heat resistance of the molded article comprising said copolymer as a base resin. (iv) (v) The weight average molecular weight (Mw), the number average molecular weight (Mn) and the ratio thereof (Mw/Mn) can be determined at 135.degree. C. by a gel permeation chromatography (GPC: e.g., GPC-150C manufactured by Waters Co., Ltd.) with a mixed polystyrene gel column (e.g., PSgel GMH6-HT manufactured by Toso K. K.) using a solution of 0.05% by weight of the polymer in o-dichlorobenzene. The weight average molecular weight (Mw) of the propylene/ethylene random copolymer according to the present invention is in the range of 40,000 to 1,000,000, preferably 100,000 to 1,000,000. The ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) represents a molecular weight distribution width, i.e., the dispersity of the propylene/ethylene random copolymer. The dispersity (Mw/Mn) of the propylene/ethylene random copolymer according to the present invention is in the range of 1.5 to 3.5, preferably 1.5 to 2.5. (vi) The melt flow rate (MFR) of the propylene/ethylene random copolymer is determined as an indication of flowability of the resin, i.e., processability. For the propylene/ethylene random copolymer having the above-mentioned various characteristics according to the present invention, the melt flow rate (MFR) determined at a temperature of 230.degree. C. and a load of 21.18N according to the condition 14 in Table 1 of JIS K7210 is 1 g/10 min or higher, preferably 20 g/10 min or higher, most preferably 30-50 g/10 min. (vii) For the propylene/ethylene random copolymer of the present invention, the melting point (Tm) determined using a differential scanning calorimeter (DSC: e.g., DCS 7 type manufactured by Perkin Elmer Co., Ltd.) is in the range of 100 to 160.degree. C., preferably 100 to 150.degree. C., more preferably 100 to 140.degree. C. The melting point (Tm) of the polymer by the above DSC is a value determined as a temperature showing a peak on melting which was determined by heating the polymer from room temperature to 230.degree. C. at a rate of 30.degree. C./min, keeping it at 230.degree. C. for 10 minutes, followed by lowering to -20.degree. C. at a rate of 20.degree. C./min, keeping it at -20.degree. C. for further 10 minutes and heating it again at a rate of 20.degree. C./min. The propylene/ethylene random copolymer having the above-mentioned various characteristics according to the present invention can be produced by copolymerizing propylene and ethylene in the presence of a supported metallocene catalyst comprising a transition metal compound and an aluminoxane or the reaction product thereof supported on a fine particle support and an organoaluminum compound. The transition metal compound is represented by the following formula ##STR2## wherein M represents a transition metal atom selected from the group consisting of titanium, zirconium and hafnium; X and Y may be the same or different and each represents a hydrogen atom, a halogen atom or a hydrocarbyl radical; (C.sub.5 H.sub.4-m R.sup.1.sub.m) and (C.sub.5 H.sub.4-n R.sup.2.sub.n) represent a substituted cyclopentadienyl group in which m and n are an integer of 1-3; R.sup.1 and R.sup.2 may be the same or different and each represents a hydrocarbyl radical of 1 to 20 carbons or a silicone-containing hydrocarbyl radical, with the proviso that the position of R.sup.1 and R.sup.2 on the cyclopentadienyl ring gives a configuration wherein any symmetry plane containing M each other is absent; and Q is a divalent hydrocarbyl radical, an unsubstituted silylene group and a hydrocarbyl-substituted silylene group. More specifically, the halogen atoms represented by X and Y in the formula include fluorine, chlorine, bromine and iodine, the hydrocarbyl radicals include an alkyl group such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, sesquibutyl, tertiary butyl, pentyl, heptyl, hexyl, octyl, 2-ethylhexyl, nonyl, decyl, dodecyl, octadecyl, etc.; a halogenated alkyl group wherein a part or all of the hydrogen atoms in the alkyl group are substituted by said halogen atom; an unsubstituted or substituted cycloalkyl group which may be substituted by said halogen atom, said alkyl or halogenated alkyl group, such as cyclopentyl, cyclohexyl, etc.; an unsubstituted or substituted aryl group which may be substituted by said halogen atom, said alkyl or halogenated alkyl group, such as phenyl, naphthyl, benzyl, etc.; an alkoxy group such as methoxy, ethoxy, isopropoxy, butoxy, etc.; a halogenated alkoxy group; and an unsubsituted or substituted aryloxy group such as phenoxy, benzyloxy, etc. The hydrocarbyl radicals of 1 to 20 carbons represented by R.sup.1 and R.sup.2 in the above formula are the same groups as recited above, and the silicone-containing hydrocarbyl radicals include a trialkylsilyl group such as trimethylsilyl, triethylsilyl, dimethylethylsilyl, methyldiethylsilyl, etc.; a silylalkyl group such as trimethylsilylmethyl, triethylsilylethyl, etc.; and a silyloxy group such as trimethylsilyloxy, triethylsilyloxy, etc. The position of the substituents R.sup.1 and R.sup.2 on two cyclopentadienyl rings gives a configuration wherein any symmetry plane containing M each other is absent. It is preferable that at least one of R.sup.1 and R.sup.2 is attached to the carbon adjacent to the carbon attached to Q on the cyclopentadienyl ring. The divalent hydrocarbyl groups represented by Q in the above formula include an alkylene group such as methylene, ethylene, 1,3-propylene, 1,2-propylene, 2,2-propylene, etc.; an arylene group such as phenylene, naphthylene, etc. The hydrocarbon-substituted silylene groups include those substituted by the above hydrocarbyl radical, such as dimethylsilylene, diethylsilylene, methylethylsilylene, methylphenylsilylene, etc. As a transition metal compound, any compound of the above formula can be used, for example, dimethylsilylene(2,4-dimethylcyclopentadienyl)(3',5'-dimethylcyclopentadie nyl)titanium dichloride, dimethylsilylene(2,4-dimethylcyclopentadienyl)(3',5'-dimethylcyclopentadie nyl)zirconium dichloride, dimethylsilylene(2,4-dimethylcyclopentadienyl)(3',5'-dimethylcyclopentadie nyl)hafnium dichloride, dimethylsilylene(2,4-dimethylcyclopentadienyl)(3',5'-dimethylcyclopentadie nyl)titanium dimethyl, dimethylsilylene(2,4-dimethylcyclopentadienyl)(3',5'-dimethylcyclopentadie nyl)zirconium dimethyl, dimethylsilylene(2,4-dimethylcyclopentadienyl)(3',5'-dimethylcyclopentadie nyl)hafnium dimethyl, dimethylsilylene(2-methyl-4-t-butylcyclopentadienyl)(3'-methyl-5'-t-butylc yclopentadienyl)zirconium dichloride, dimethylsilylene(2-methyl-4-trimethylsilylcyclopentadienyl)-(3'-methyl-5'- trimethylsilylcyclopentadienyl)zirconium dichloride, dimethylsilylene(2,3,5-trimethylcyclopentadienyl)(2',4',5'-trimethylcyclop entadienyl)titanium dichloride, dimethylsilylene(2,3,5-trimethylcyclopentadienyl)(2', 4',5'-trimethylcyclopentadienyl)zirconium dichloride, dimethylsilylene(2,3,5-trimethylcyclopentadienyl)(2',4',5'-trimethylcyclop entadienyl)zirconium dimethyl, dimethylsilylene(2,3,5-trimethylcyclopentadienyl)(2',4',5'-trimethylcyclop entadienyl)hafnium dichloride, dimethylsilylene(2,3,5-trimethylcyclopentadienyl)(2',4',5'-trimethylcyclop entadienyl)hafnium dimethyl, etc. In particular, dimethylsilylene(2,3,5-trimethylcyclopentadienyl)(2',4',5'-trimethylcyclop entadienyl)zirconium dichloride is preferably used. The aluminoxane is an organic radical-containing aluminum compound represented by formula (1) or (2). ##STR3## wherein R.sup.3 s are a hydrocarbyl radical of 1 to 6 carbons, preferably 1 to 4 carbons, e.g., an alkyl group such as methyl, ethyl, propyl, butyl, isobutyl, pentyl, hexyl, etc.; an alkenyl group such as allyl, 2-methylallyl, propenyl, isopropenyl, 2-methyl-1-propenyl, butenyl, etc.; a cycloalkyl group such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, etc.; and an aryl group, etc.; and each R.sup.3 may be the same or different. Preferable R.sup.3 is an alkyl group. q is an integer of 4 to 30, preferably 6 to 30, and more preferably 8 to 30. The above-mentioned aluminoxanes may use commercially available products, and also they may be prepared by known methods. The aluminoxanes can be prepared, for example, by the following methods: A method of reacting a trialkyl aluminum, e.g., trimethyl aluminum, triisobutyl aluminum or the mixture thereof, directly with water in an organic solvent such as toluene, ether, etc.; A method of reacting a trialkyl aluminum, e.g., trimethyl aluminum, triisobutyl aluminum or the mixture thereof, with salts containing crystal water, e.g., copper sulfate hydrate and aluminum sulfate hydrate; and A method of reacting water impregnated in silica gel or the like, with a trialkyl aluminum, e.g., trimethyl aluminum, triisobutyl aluminum, separately or simultaneously or successively. The fine particle supports, on which the transition metal compound and aluminoxane or the reaction product thereof are supported, are granulated or spherical, inorganic or organic solid fine particles having a particle diameter of 1 to 500 .mu.m, preferably 5 to 300 .mu.m. The inorganic fine particle supports used are fine particles of metal oxides, e.g., SiO.sub.2, Al.sub.2 O.sub.3, MgO, ZrO.sub.2, TiO.sub.2, etc., and the mixture thereof or the composite oxides thereof. Preferable are fine particles comprising as a main component at least one selected from the group consisting of SiO.sub.2, Al.sub.2 O.sub.3 and MgO. For instance, SiO.sub.2, Al.sub.2 O.sub.3, MgO, SiO.sub.2 --Al.sub.2 O.sub.3, SiO.sub.2 --MgO, SiO.sub.2 --TiO.sub.2, SiO.sub.2 --Al.sub.2 O.sub.3 --MgO, etc. are preferably used. These inorganic fine particle supports are used after fired usually at a temperature of 100 to 1000.degree. C. for 1 to 40 hours. Instead of firing, they may be used after chemically dehydrated, e.g., with SiCl.sub.4, chlorosilane, etc. The organic fine particle supports which can be used include polymer fine particles such as polyolefin polymer fine particles, e.g., polyethylene, polypropylene, poly(1-butene), poly(4-methyl-1-pentene), polystyrene fine particles, etc. The supported metallocene catalyst is prepared by reacting the transition metal compound with aluminoxane in the presence of the fine particle support. In general, the desired, supported metallocene catalysts can be prepared by contacting a transition metal compound and aluminoxane soluble in a hydrocarbon solvent with a dehydrated fine particle support to deposit the transition metal compound and aluminoxane or the reaction product thereof on the fine particle support. The order for contacting the transition metal compound and aluminoxane with the fine particle support can be varied arbitrarily, with no particular limitation. The desired, supported metallocene catalyst can be prepared, for instance, by any of the methods which include a method of initially adding a solution of a transition metal compound dissolved in a suitable hydrocarbon solvent to a fine particle support and subsequently adding aluminoxane; a method of adding a reaction product of a transition metal compound and aluminoxane to a fine particle support; and a method of initially adding aluminoxane to a fine particle support, followed by adding a transition metal compound. The ratio of the transition metal compound to aluminoxane supported on the fine particle support is 12 to 1000 mol, preferably 50 to 500 mol in terms of Al atom derived from aluminoxane, per mole of a transition metal atom derived from the transition metal compound. The reaction conditions include the reaction temperature of usually -20 to 100.degree. C., preferably 0 to 100.degree. C. and the reaction time of usually 0.1 minute or more, and preferably 1 to 200 minutes. The supported metallocene catalyst is preferably used for the copolymerization of propylene and ethylene, after it has been pre-activated by prepolymerizing small amounts of olefins on the supported metallocene catalyst. The olefins used for the pre-activation include ethylene, propylene, 1-butene, 1-hexene, 3-methyl-1-butene, 4-methyl-1-pentene, etc. and the mixture thereof. The polymerization amount of olefins for the pre-activation of the supported metallocene catalyst is usually 10 to 1000 wt %, preferably 30 to 300 wt %, more preferably 30 to 100 wt %, based on the supported metallocene catalyst. An olefin polymerization catalyst comprises the supported metallocene catalyst, preferably the preactivated, supported metallocene catalyst, and the organoaluminum compound. The organoaluminum compound acts as a scavenger. Such organoaluminum compounds include, e.g., triethylaluminum, tri-isopropylaluminum, tri-isobutylaluminum, tri-n-butylaluminum, tri-n-hexylaluminum, di-isobutylaluminum hydride and the mixtures thereof. In particular, triethylaluminum and tri-isobutylaluminum are preferably used. The propylene/ethylene random copolymer of the present invention can be produced by copolymerizing propylene and ethylene in the presence of the olefin polymerization catalyst comprising the supported metallocene catalyst, preferably the preactivated, supported metallocene catalyst, and the organoaluminum compound. As a process for the copolymerization of propylene and ethylene, known polymerization processes of propylene can be employed, for example, a slurry polymerization process wherein propylene is polymerized in an inert solvent including an aliphatic hydrocarbon such as butane, pentane, hexane, heptane and isooctane, an alicyclic hydrocarbon such as cyclopentane, cyclohexane and methylcyclohexane, an aromatic hydrocarbon such as toluene, xylene and ethylbenzene, and gasoline fraction and hydrogenated diesel oil; a bulk polymerization process wherein propylene itself is used as a solvent; a gas phase polymerization process wherein propylene is polymerized in a gas phase; a solution polymerization process wherein a liquid polypropylene is formed; and a combination of these two or more polymerization processes. As the conditions for the copolymerization of propylene and ethylene in the above polymerization process, similar conditions to those in the olefin polymerization using a Ziegler-Natta catalyst system are usually employed. More specifically, the polymerization temperature ranges from -50 to 150.degree. C., preferably -10 to 100.degree. C., more preferably 40 to 80.degree. C. The polymerization pressure ranges from atomospheric pressure to 7 MPa, preferably 0.2 to 5 MPa. The polymerization time is usually about one minute to 20 hrs. The molecular weight of the resulting propylene/ethylene random copolymer can be controlled by choice of the polymerization conditions as mentioned above, but it may be controlled, if desired, by introducing a molecular weight modifier, e.g., hydrogen into the polymerization system. In the copolymerization of propylene and ethylene, other monomers than ethylene and propylene may be copolymerized to a degree not impairing the effect of the propylene/ethylene random copolymer according to the present invention. A copolymerizable monomer includes, but not limited to, olefins of 4-20 carbons, e.g., 1-butene, 1-pentene, 1-hexene, 1-octene, 1-decene, 4-methyl-1-pentene, 3-methyl-1-pentene, etc. and the mixture thereof. In particular, 1-butene is preferably used. In addition to these olefins, small amounts of .alpha.,(.omega.-dienes such as 1,5-hexadiene, 1,9-decadiene may be copolymerized. After the completion of the copolymerization reaction of propylene and ethylene, the propylene/ethylene random copolymer with the above-mentioned various characteristics is produced through known after-treatment steps of deactivating the catalyst, removing the catalyst residue, drying, and the like. The first embodiment of the molding material in the present invention is the propylene composition (called hereafter "first molding material") comprising the propylene/ethylene random copolymer with the above-mentioned various characteristics and a desired additive component. The additive components include various additives generally incorporated in the polypropylene resin composition, and synthetic resins or the like. These additives include, for example, antioxidants such as phenol-, thioether- or phosphorus-antioxidants; ultraviolet absorbing agents; heat stabilizers; heavy metal inactivators (copper pollution inhibitors); clarifiers; antistatic agents; nucleating agents; lubricants; anti-fogging agents; flame retardants; auxiliaries for flame retardants; antiblocking agents; anti-dropping agents; radical generators; pigments; colorants; halogen scavengers; dispersing agents or neutralizing agents such as metal soaps; organic or inorganic antibacterial agents; inorganic fillers, e.g., talc, mica, clay, wollastonite, zeolite, kaolin, bentonite, pearlite, diatomaceous earth, asbestos, calcium carbonate, magnesium carbonate, aluminum hydroxide, magnesium hydroxide, hydrotalcite, basic aluminum lithium hydroxycarbonate hydrate, silicon dioxide, titanium dioxide, zinc oxide, magnesium oxide, calcium oxide, zinc sulfide, barium sulfate, magnesium sulfate, calcium silicate, aluminum silicate, glass fibers, potassium titanate, carbon fibers, carbon black, graphite and metallic fibers; organic fillers, e.g., wood flour, pulp, wastepaper, synthetic fibers and natural fibers; coupling agents, e.g., silane-, titanate-, boron-, aluminate- or zircoaluminate-coupling agents; and the inorganic or organic fillers which are surface-treated with any of the coupling agents. The synthetic resins which can be added include, for example, polyethylene such as HDPE, LDPE, LLDPE and VLLDPE or ethylene copolymers; polyolefins such as polypropylene, poly(1-butene), poly(1-pentene), poly(1-hexene), poly(1-octene), poly(1-decene), poly(4-methyl-1-pentene) and poly(3-metyl-1-pentene); olefin random or block copolymers such as ethylene/propylene, ethylene/1-butene, propylene/1-butene and ethylene/propylene/1-butene; rubber components such as polybutadiene, polyisoprene, natural rubbers and the hydrogenated products thereof; olefin elastomers, a typical example of which is EPR, EBR, EHR, EOR, EPDM, CEBC and PBR; styrene elastomers, a typical example of which is HSBR, SEP, SEB, SEPS, SEBS and SEBC; nylon; polycarbonate; ABS; polystyrene; and maleic anhydride modified propylene polymers. These additive components are selected suitably depending on the purpose of molding. As mentioned above, the first molding material is a propylene composition comprising the propylene/ethylene random copolymer as a base resin, into which a prescribed amount of the additive components is incorporated as required depending on the purpose of molding. In general, the first molding materials are provided for the formation of films, sheets, injection moldings, extrusion moldings, blow moldings, fibers, etc. in the form of pellets prepared by compounding the base resin with a prescribed amount of the desired additive component, subjecting the compound to melt-kneading, followed by cutting into granulates. The melt-kneading temperature is usually 170 to 300.degree. C., preferably 180 to 270.degree. C. Conventional mixing apparatus such as Henschel mixer (trade name), Super mixer, ribbon blender and Banbury mixer, a single screw extruder, a double-screw extruder, Brabender, roll, etc. are used for melt-kneading and pelletizing. The second embodiment of the molding material in the present invention is the propylene/ethylene random copolymer composition (called hereafter "second molding material") comprising the propylene/ethylene random copolymer, an .alpha.-crystal nucleating agent of 0.0001 to 1 part by weight based on 100 parts by weight of the copolymer, and a desired additive component. That is, the second molding material is the composition wherein a prescribed amount of .alpha.-crystal nucleating agent is incorporated into the first molding material. The .alpha.-crystal nucleating agent accelerates the crystallization of the-propylene/ethylene random copolymer as a base resin, and improves the stiffness, heat resistance, and further, transparency of the molded articles. If the amount of .alpha.-crystal nucleating agent incorporated is too little, the crystallization of the propylene/ethylene random copolymer becomes insufficient, resulting in unsatisfactory improvement of the stiffness and heat resistance of the molded articles. If the amount is too much, the transparency of the molded article is lowered. The amount of .alpha.-crystal nucleating agent incorporated is preferably 0.01 to 0.5 part by weight, more preferably 0.05 to 0.3 part by weight. The .alpha.-crystal nucleating agents to be used include inorganic compounds; carboxylic acids except for aliphatic monocarboxylic acids; normal or basic salts thereof; dibenzylidenesorbitol compounds; arylphosphate compounds; mixtures of cyclic polyvalent metal aryl phosphate compounds and alkali metal salts of aliphatic monocarboxylic acids or basic aluminum lithium hydrocarbonate hydrate; polymeric compounds; and the mixtures thereof. The inorganic compounds include, e.g., talc, alum, silica, titanium oxide, calcium oxide, magnesium oxide, carbon black, clay minerals or the like. The carboxylic acids except for aliphatic monocarboxylic acids include, e.g., malonic acid, succinic acid, adipic acid, maleic acid, azelaic acid, sebacic acid, dodecanic diacid, citric acid, butanetricarboxylic acid, butanetetracarboxylic acid, naphthenic acid, cyclopentanecarboxylic acid, 1-methylcyclopentanecarboxylic acid, 2-methylcyclopentanecarboxylic acid, cyclopentenecarboxylic acid, cyclohexanecarboxylic acid, 1-methylcyclohexanecarboxylic acid, 4-methylcyclohexanecarboxylic acid, 3,5-dimethylcyclohexanecarboxylic acid, 4-butylcyclohexane-carboxylic acid, 4-octylcyclohexanecarboxylic acid, cyclohexenecarboxylic acid, 4-cyclohexene-1,2-dicarboxylic acid, benzoic acid, toluic acid, xylic acid, ethylbenzoic acid, 4-t-butylbenzoic acid, salicylic acid, phthalic acid, trimellitic acid, pyromellitic acid or the like. Their normal or basic salts include salts of lithium, sodium, potassium, magnesium, strontium, barium, zinc or aluminum. Dibenzylidenesorbitol compounds include, e.g., 1.3,2.4-dibenzylidenesorbitol, 1.3-benzylidene-2.4-p-methylbenzylidenesorbitol, 1.3-benzylidene-2.4-p-ethylbenzylidenesorbitol, 1.3-p-methylbenzylidene -2.4-benzylidenesorbitol, 1.3-p-ethylbenzylidene-2.4-benzylidenesorbitol, 1.3-p-methylbenzylidene-2.4-p-ethylbenzylidenesorbitol, 1.3-p-ethylbenzylidene-2.4-p-methylbenzylidenesorbitol, 1.3,2.4-bis(p-methylbenzylidene)sorbitol, 1.3,2.4-bis(p-ethylbenzylidene)sorbitol, 1.3,2.4-bis(p-n-propylbenzylidene)sorbitol, 1.3,2.4-bis(p-i-propylbenzylidene)sorbitol, 1.3,2.4-bis(p-n-butylbenzyli-dene)sorbitol, 1.3,2.4-bis(p-s-butylbenzylidene)sorbitol, 1.3,2.4-bis(p-t-butylbenzylidene)sorbitol, 1.3-(2'.4'-dimethylbenzylidene)-2.4-benzylidenesorbitol, 1.3-benzylidene-2.4-(2'.4'-dimethylbenzylidene)sorbitol, 1.3,2.4-bis(2',4'-dimethylbenzylidene)sorbitol, 1.3,2.4-bis(3',4'-dimethylbenzylidene)sorbitol, 1.3,2.4-bis(p-methoxybenzylidene)sorbitol, 1.3,2.4-bis(p-ethoxybenzylidene)sorbitol, 1.3-benzylidene-2.4-p-chlorobenzylidenesorbitol, 1.3-p-chlorobenzylidene-2.4-benzylidenesorbitol, 1.3-p-chlorobenzylidene-2.4-p-methylbenzylidenesorbitol, 1.3-p-chlorobenzylidene-2.4-p-ethylbenzylidenesorbitol, 1.3-p-methylbenzylidene-2.4-p-chlorobenzylidenesorbitol, 1.3-p-ethylbenzylidene-2.4-p-chlorobenzylidenesorbitol, 1.3,2.4-bis(p-chlorobenzylidene)-sorbitol or the like. The arylphosphate compounds include, e.g., lithium bis(4-t-butylphenyl)phosphate, sodium bis(4-t-butylphenyl)phosphate, lithium bis(4-cumylphenyl)phosphate, sodium bis(4-cumylphenyl)phosphate, potassium bis(4-t-butylphenyl)phosphate, calcium mono(4-t-butylphenyl)phosphate, calcium bis(4-t-butylphenyl)phosphate, magnesium mono(4-t-butylphenyl)phosphate, magnesium bis(4-t-butylphenyl)phosphate, zinc mono(4-t-butylphenyl)phosphate, aluminum dihydroxy-(4-t-butylphenyl)phosphate, aluminum hydroxy-bis(4-t-butyl-phenyl)phosphate, aluminum tris(4-t-butylphenyl)phosphate, sodium 2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate, sodium 2,2'-ethylidene-bis(4,6-di-t-butylphenyl)phosphate, sodium 2,2'-methylene-bis(4-cumyl-6-t-butylphenyl)phosphate, lithium 2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate, lithium 2,2'-ethylidene-bis(4,6-di-t-buthylphenyl)phosphate, lithium 2,2'-methylene-bis(4-cumyl-6-di-t-butylphenyl)phosphate, sodium 2,2'-ethylidene-bis(4-i-propyl-6-di-t-butylphenyl)phosphate, lithium 2,2'-methylene-bis(4-methyl-6-di-t-butylphenyl)phosphate, lithium 2,2'-methylene-bis(4-ethyl-6-di-t-butylphenyl)phosphate, sodium 2,2'-butylidene-bis(4,6-di-methylphenyl)phosphate, sodium 2,2'-butylidene-bis(4,6-di-t-butylphenyl)phosphate, sodium 2,2'-t-octylmethylene-bis(4,6-di-methylphenyl)-phosphate, sodium 2,2'-octylmethylene-bis(4,6-di-t-butylphenyl)phosphate, sodium 2,2'-methylene-bis(4-methyl-6-di-t-butylphenyl)phosphate, sodium 2,2'-methylene-bis(4-ethyl-6-di-t-butylphenyl) phosphate, sodium (4,4'-dimethyl-6,6'-di-t-butyl-2,2'-biphenyl)phosphate, sodium 2,2'-ethylidene-bis(4-s-butyl-6-t-butylphenyl)phosphate, sodium 2,2'-methylene-bis(4,6-di-methylphenyl)phosphate, sodium 2,2'-methylene-bis(4,6-di-ethylphenyl)phosphate, potassium 2,2'-ethylidene-bis(4,6-di-t-butylphenyl)phosphate, etc. The cyclic polyvalent metal aryl phosphate compounds include calcium bis[2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate], magnesium bis[2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate], zinc-bis[2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate], aluminum tris[2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate], calcium-bis[2,2'-methylene-bis(4-methyl-6-t-butylphenyl)-phosphate], calcium bis[2,2'-thiobis(4-methyl-6-t-butylphenyl)phosphate], calcium-bis[2,2'-thiobis(4-ethyl-6-t-butylphenyl)phosphate], calcium bis[2,2'-thiobis(4,6-di-t-butylphenyl)phosphate], magnesium bis[2,2'-thiobis(4,6-di-t-butylphenyl)phosphate], magnesium bis[2,2'-thiobis(4-t-octylphenyl)phosphate], barium bis[2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate], calcium bis[(4,4'-dimethyl-6,6'-di-t-butyl-2,2'-biphenyl)phosphate], magnesium bis[2,2'-ethylidene-bis(4,6-di-t-butylphenyl)phosphate], barium bis[2,2'-ethylidene-bis(4,6-di-t-butylphenyl)phosphate], aluminum tris[2,2'-ethylidene-bis(4,6-di-t-butylphenyl)phosphate], aluminum dihydroxy-2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate, aluminum dihydroxy-2,2'-methylene-bis(4-cumyl-6-t-butylphenyl)phosphate, aluminum hydroxy-bis[2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate], aluminum hydroxy-bis[2,2'-methylene-bis(4-cumyl-6-t-butylphenyl)phosphate], titanium dihydroxy-bis[2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate], tin dihydroxy-bis[2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate], zirconium oxy-bis[2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate, aluminum dihydroxy-2,2'-methylene-bis(4-methyl-6-t-butylphenyl)phosphate, aluminum hydroxy-bis[2,2'-methylene-bis(4-methyl-6-t-butylphenyl)phosphate], aluminum dihydroxy-2,2'-ethylidene-bis(4,6-di-t-butylphenyl)phosphate, aluminum hydroxy-bis[2,2'-ethylidene-bis(4,6-di-t-butylphenyl)phosphate] and the like. The alkali metal salts of aliphatic monocarboxylic acids which are used in admixture with the cyclic polyvalent metal aryl phosphate compounds include lithium, sodium or potassium salts of aliphatic monocarboxylic acids such as acetic acid, lactic acid, propionic acid, acrylic acid, octanoic acid, isooctanoic acid, nonanoic acid, decanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, 12-hydroxystearic acid, ricinolic acid, behenic acid, erucic acid, montanoic acid, melissic acid, stearoyllactic acid, .beta.-dodecylmercaptoacetic acid, .beta.-dodecylmercaptopropionic acid, .beta.-N-laurylaminopropionic acid, .beta.-N-methyl-lauroylamino-propionic acid and the like. The mixture of the cyclic polyvalent metal aryl phosphate compounds and basic aluminum lithium hydrocarbonate hydrate is also included. The polymeric compounds include, e.g., poly(3-methyl-1-butene), poly(3-methyl-1-pentene), poly(4-methyl-1-pentene), poly(4-methyl-1-hexene), poly(4,4-dimethyl-1-pentene), poly(4,4-dimethyl-1-hexene), poly(4-ethyl-1-hexene), poly(3-ethyl-1-hexene), polyallylnaphthalene, polyallylnorbornane, atactic polystyrene, syndiotactic polystyrene, polydimethylstyrene, polyvinylnaphthalene, polyallylbenzene, polyallyltoluene, polyvinylcyclopentane, polyvinylcyclohexane, polyvinylcycloheptane, polyvinyltrimethylsilane, polyallyltrimethylsilane and the like. Particularly preferable .alpha.-crystal nucleating agents include talc, aluminum hydroxy-bis(4-t-butylbenzoate), 1.3,2.4-dibenzylidenesorbitol, 1.3,2.4-bis(p-methylbenzylidene)sorbitol, 1.3,2.4-bis(p-ethyl-benzylidene)sorbitol, 1.3,2.4-bis(2',4'-dimethyl-benzylidene)-sorbitol, 1.3,2.4-bis(3',4'-dimethyl-benzylidene)sorbitol, 1.3-p-chlorobenzylidene-2.4-p-methylbenzylidene)sorbitol, 1.3,2.4-bis(p-chlorobenzylidene)sorbitol; sodium bis(4-t-butylphenyl)phosphate, sodium 2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate, cyclic polyvalent metal arylphosphate compounds, e.g., calcium 2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate, aluminum 2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate, aluminum dihydroxy-2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate or mixtures of aluminum hydroxy-bis[2,2'-methylene-bis(4,6-di-t-butylphenyl)phosphate] and alkali metal salts of the aliphatic monocarboxylic acids, poly(3-methyl-1-butene), polyvinylcyclohexane, triallyltrimethylsilane; and the mixture thereof. The second molding materials can be suitably used in the manufacture of molded articles according to various molding methods such as injection, extrusion and blow molding methods. The third embodiment of the molding materials in the present invention is a polypropylene/ethylene random copolymer composition (called hereafter "third molding material") comprising the polypropylene/ethylene random copolymer, a radical generator of 0.001 to 0.5 part by weight based on 100 parts by weight of the copolymer, and a desired additive component. That is, the third material is a composition wherein a prescribed amount of the radical generator is incorporated into the first molding material. The third molding material is melt-kneaded at 150-300.degree. C. for modification, thereby giving a polypropylene/ethylene random copolymer composition having a controlled melt flow rate (MFR). The radical generator added to the polypropylene/ethylene random copolymer can control the melt flow rate (MFR) of the composition to a desired value, while maintaining the melting point (Tm) and dispersity (Mw/Mn) of the propylene/ethylene random copolymer which is a base resin by melt-kneading. As a result, the processability of the composition is improved. If the amount of the radical generator incorporated is too little, the effect of controlling MFR becomes insufficient. If it is too much, the composition cannot maintain its characteristics as mentioned above. The amount of the radical generator incorporated is usually 0.001 to 0.5 part by weight, preferably 0.01 to 0.2 part by weight, based on 100 parts by weight of the base resin. It is required to melt-knead the base resin and the radical generator at a suitable temperature so that the radical generator can achieve the above-mentioned function. If the melt-kneading temperature is too low, the effect of modifying the composition becomes insufficient. If it is too high, a coloration of the composition becomes remarkable. The melt-kneading temperature is usually 150 to 270.degree. C., preferably 180 to 270.degree. C. For the radical generator which acts as mentioned above, it is desirable that the decomposition temperature is not too low to obtain a uniform mixed composition. The temperature for obtaining a half-life period of 10 hours is 70.degree. C. or higher, preferably 100.degree. C. or higher. Such radical generators include organic peroxides such as, e.g., benzoyl peroxide, t-butyl peroxide, t-butylperacetate, t-butylperoxyisopropylcarbonate, 2,5-dimethyl-2,5-di(benzoylperoxy)hexane, 2,5-dimethyl-2,5-di(benzoylperoxy)hexyne-3, t-butyl-di-peradipate, t-butylperoxy-3,5,5-trimethylhexanoate, methyl ethyl ketone peroxide, cyclohexanone peroxide, di-t-butyl peroxide, dicumyl peroxide, 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, 2,5-dimethyl-2,5-di(t-butylperoxy)hexyne-3, 1,3-bis(t-butylperoxyisopropyl)benzene, t-butylcumyl peroxide, 1,1-bis(t-butylperoxy)-3,5,5-trimethylcyclohexane, 2,2-bis(t-butylperoxy)butane, p-methane hydroperoxide, di-isopropylbenzene hydroperoxide, cumene hydroperoxide, t-butyl hydroperoxide, p-cymene hydroperoxide, 1,1,3,3-tetramethyl-butyl hydroperoxide, 2,5-dimethyl-2,5-di(hydroperoxy)hexane, trimethylsilyl-cumylperoxide, 2,5-dimetyl-2,5-bis(trimethylsilylperoxy)hexane, 2,5-dimetyl-2,5-bis(trimethylsilylperoxy)hexyne-3, 1,3-bis(trimethyl-silylperoxyisopropyl)benzene, and the mixtures thereof. Particularly preferable radical generators are 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, 2,5-dimethyl-2,5-di(t-butylperoxy)hexyne-3 and 1,3-bis(t-butylperoxy-isopropyl)benzene and the mixture thereof. In the third molding material, MFR of the composition is controlled to a desired value by melt-kneading radical generators, while maintaining the melting point (Tm) and dispersity (Mw/Mn) of the propylene/ethylene random copolymer as a base resin. Thus, the processability can be controlled arbitrarily. The molded articles formed therefrom maintain various mechanical properties peculiar to the propylene/ethylene random copolymer, e.g., strength, elastic modulus, Young's modulus, elongation, etc. When the third molding materials having controlled MFR are used in the manufacture of fibers, a spinning speed is efficiently improved and the fibers of small fineness, e.g., filament, staple, monofilament, tow, etc. can be efficiently produced by spun bond and melt blown processes. Further, the third molding materials can be used suitably as molding materials for films, sheets, injection moldings, etc. including conjugates with other polymers such as polypropylene, and various fibers such as dyeable type, colored type, modified cross section type and hollow type. The molded articles in the present invention include those formed from the above propylene composition (first molding material) such as films, sheets, injection moldings, extrusion moldings, blow moldings, fibers, etc. The films in the present invention are those having a thickness of usually 1 to 150 .mu.m, preferably 10 to 90 .mu.m, formed from the above propylene composition (first molding material). As a method of forming a film, known T-die and tubular methods, etc. can be employed. A film-forming condition which can be used is similar to a conventional film-forming condition of a polypropylene film. The melt-extruded film is quenched at 90.degree. C. or below. Quenching from a temperature exceeding 90.degree. C. is not desirable, since it embrittles the film and lowers a low temperature heat-sealing property. The films include any of unstretched films, uniaxially stretched films and biaxially oriented films. Those films have excellent-heat resistance and stiffness, and high transparency, since they comprise the propylene/ethylene random copolymer as a base resin. Another embodiment of the present film is a composite polypropylene film comprising the above-mentioned film layer and other polypropylene film layer. The composite polypropylene films include, e.g., those formed by a method of extruding and laminating an unstretched film of the first molding material on another polypropylene film, e.g., a crystalline polypropylene film and those formed by co-extruding the first molding material and other polypropylene composition by T-die and tubular methods. These composite polypropylene films may be any of unstretched films, uniaxially stretched films and biaxially oriented films. Particularly preferred embodiment of the present composite polypropylene film is an stretched multi-layer polypropylene film having a heat-seal layer comprising a film layer formed from the first molding material on at least one surface of the base layer comprising a crystalline polypropylene as a main component. The multi-layer polypropylene film is the film which is stretched to the longitudinal direction usually by 3-6 times, preferably 4.0-5.5 times. Preferably, it is also stretched to the transverse direction by 6-10 times, preferably 7.0-9.0 times. In particular, the film, which is excellent in stiffness, is prepared by stretching to the longitudinal direction by 4.0-5.5 times. The thickness of the multi-layer polypropylene film is chosen depending on the purpose, but is usually 5 to 100 .mu.m, preferably 10 to 60 .mu.m. The thickness of the heat-seal layer is chosen depending on the purpose, but is usually 0.5 to 10 .mu.m, preferably 0.7 to 5.0 .mu.m. The heat-seal layer is the film layer formed from the above propylene composition (first molding material). The basic layer is a film layer formed from a molding material which comprises a crystalline polypropylene as a main component with a desired additive incorporated, the crystalline polypropylene having higher melting point than the propylene/ethylene random copolymer which is a base resin of the heat-seal layer. As the crystalline polypropylenes which are a main component for the basic layer, known polypropylenes for film satisfying the condition of the melting point as mentioned above can be used with no particular limitation, but polypropylenes are preferably used which have an isotactic index (I.I.: boiling n-heptane insoluble component) of 75% or more, preferably 85 to 99%. More preferably, these crystalline polypropylenes have the density of 0.89 to 0.92 g/cm.sup.3 and the melt flow rate (MFR) of 0.1 to 10 g/10 min. Crystalline polypropylenes are usually homopolypropylenes, but propylene/olefin random copolymers can be used which contain an olefin monomer unit in the range not impairing the object of the present invention, e.g., not more than 5 mol %. Olefins copolymerizable with propylene include .alpha.-olefins of 2-20 carbons, e.g., ethylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 4-methyl-1-pentene, etc. The processes of preparing crystalline polypropylenes can employ known processes using a Ziegler-Natta catalyst system or a metallocene catalyst system, with no particular limitation thereto. The desired additives constituting the basic layer include, e.g., thermostabilizer, inorganic filler, slip agent, antistatic agent and the like. These can be used in the range not impairing the purpose of the present invention. As the process of preparing the multi-layer polypropylene film, known processes can be employed which include, e.g., a process of co-extruding the molding material for the basic layer and the molding material for the heat-seal layer, followed by stretching, a process of laminating the heat-seal layer film on the basic layer film stretched to the longitudinal direction, followed by stretching to the transverse direction, and the like. As the method of stretching the film, known methods can be employed such as a tubular method, a tentering method and the like. The stretched, multi-layer polypropylene films of the present invention are excellent in transparency, blocking resistance and heat-sealing properties, since the molding materials constituting the heat-seal layer comprise the propylene/ethylene random copolymer as a base resin. The molded products of the present invention are injection moldings formed from the molding materials of the first and second embodiments as mentioned above. These injection moldings have high stiffness and heat resistance, and excellent transparency, since they comprise the propylene/ethylene random copolymer as a base resin. In particular, the injection moldings formed from the molding material of the second embodiment, the propylene/ethylene random copolymer composition have better mechanical characteristics, in particular, flexural modulus and heat resistance, and further, better transparency than injection moldings formed from the first molding materials, since the second molding materials contain the .alpha.-crystal nucleating agent. These moldings can be applied to sheets, containers, various industrial parts and the like |
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