Main > ORGANIC CHEMICALS > Aliphatics > Carbonate. > ACyclic Carbonates > Di-Tert.-Butyl TriCarbonate. > Synthesis. > Phosgene+Tert.-BuOH+CO2 Reaction

Product NE. E

FORMULA (Me)3C-O-CO-O-CO-O-CO-O-C(Me)3
UPDATE 10.99
USES Prepn of alpha,omega-ISOCYANATO ALCOHOL monomers [HO(CH2)xNCO] from alpha,omega-AMINO ALCOHOL [HO(CH2)xNH2, x = 4 to 12] under MILD conditions
A drawback, however, is that di-tert-butyl tricarbonate is UNSTABLE. “It should be stored < 4C
AUTHOR Meijer E.W. (Bert), Chem. Prof. at Eindhoven University of Technology
Sijbesma Rint P., at Eindhoven University of Technology
Versteegen Ron M., graduate student at Eindhoven University of Technology
LITERATURE REF. [Angew. Chem. Int. Ed., 38, p. 2917 (1999)]

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