Main > POLYMERS > Living (Controlled) Polymerization > Radical Polymerization > Reversible Addition-Fragmentation > Chain Transfer Polymn. (RAFT) > Polymers > Poly(Styrene). > Polystyryl dithiobenzoate. RAFT Ag. > Kinetic Study

Product Japan. K

STUDY The results show that the fragmentation of the intermediate radical, produced by the addition of the polystyryl radical to the dithiobenzoate, is a fast process and that the radical undergoes cross-termination with the polystyryl radical to form a stable, 3-arm star chain by-product, which causes retardation of the rate of polymerization
UPDATE 09.02
AUTHOR Kyoto Uni.'s Fukuda Takeshi
LITERATURE REF. Macromolecules, 35, p. 3026 (2002)

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