Main > ORGANIC CHEMICALS > Chiral Organics > Hydrogenation > Rhodium Catalyst Ligand > 1,2-BisPhospholane. Ligand. > Synthesis

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SYNTHESIS For rhodium-catalyzed hydrogenations of -(acylamino)acrylic acid derivatives and -arylenamides, author offers 1,2-bisphospholane The ligand, which has chiral phosphorus atoms, was designed with conformational rigidity in mind as well. Enantioselectivities of up to 99% and turnovers of up to 10,000 have been achieved with the ligand
UPDATE 06.02
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