Main > POLYMERS > Poly(Olefin) > Activator. CoCatal. (for Metallocen > Double Activation > > 2 equiv. Lewis Acid [Al(C6F5)3]

Product USA. D. No. 1

TECHNOLOGY Co.’s effort to reduce activator costs has yielded “DOUBLE ACTIVATION” In double activation, both Me groups of a group IV metallocene interact with > 2 equivalents of LEWIS ACID. A strong Lewis acid, Al(C6F5)3, is used to form the doubly activated species.
The chemistry is unusual, but well studied & economically worthwhile. “This well-characterized species is tremendously more efficient in promoting ETHY
LENE/OCTENE POLYMN than a monoactivated species”. Co. has found the catalysts to be 30 TIMES more active than monoactivated catalysts.
“Stronger & more efficient Lewis acid activators, such as those afforded by double activation, make for better atom economy & polymer properties as well”
UPDATE 10.01
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