Main > ORGANIC CHEMICALS > Phosphorous Organics. > Unsaturated Phosphonate Esters > Synthesis: Olefin Metathesis

Product USA. C

SYNTHESIS Compds are alternatives to P ylides. The unsaturated phosphonate does not dimerize, & such other functional groups as halide & aldehyde go unmolested
For example, diethyl ethenephosphonate reacts with 4-Br-1-butene to give diethyl 4-Br-1E-bute
ne-1-phosphonate in 82% yield & with undecylenic aldehyde to give diethyl 11-oxo-1E-undecene-1-
phosphonate in 77% yield. The group gets analogous results with diethyl propene-3-phospho
nate
UPDATE 09.01
AUTHOR This data is not available for free
LITERATURE REF. This data is not available for free

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