Main > SEPARATION > Chiral. Optical Resolution > Catalyst > Ligand

Product BINAP. BINOL. DE. R.

CORP. SALE - BINAP: 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl
- BINOL: 2,2'-bis(diphenylphosphino)-1,1'-binaphthol
COMMENTS Offers both isomers of BINAP & BINOL in > 99 % enantiomeric purity in industrial scale production at competi
tive prices
CLASSIFICATION CommPat. Market
MARKETER'S COUNTRY Germany
METHOD The process uses emulsion crystallization of microdroplets of BINOL or hydroxybenzoin in a carrier that contains N-Me & N-Et pyrrolidone & surfactants. The user seeds the emulsion with crystals of single isomer BINOL or hydroxybenzoin, & crystals of the inclusion compd of that isomer with the pyrrolidones separate out. Thus the process only resolves racemates whose inclusion compds with pyrrolidones are conglomerates & not solid solns.
PATENT ASSIGNEE'S COUNTRY Germany
PRODUCER'S COUNTRY Germany
UPDATE 07.99
USES See for example Code 2186
MARKETING BY This data is not available for free
PATENT ASSIGNEE This data is not available for free
PATENT PHOTOCOPY Available on request

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