| PATENT ASSIGNEE'S COUNTRY | Japan |
| UPDATE | 04.00 |
| PATENT NUMBER | This data is not available for free |
| PATENT GRANT DATE | 11.04.00 |
| PATENT TITLE |
Curable liquid resin composition |
| PATENT ABSTRACT |
A curable liquid resin composition containing 100 parts by weight of the following (meth)acrylic liquid resin (A) and 1 to 1,000 parts by weight of a (meth)acrylic monomer (B) having an unsaturated double bond in its molecule and having a number average molecular weight of 1,000 or less, the (meth)acrylic liquid resin (A) being a liquid resin which is obtained by polymerizing monomers containing an alkyl (meth)acrylate monomer (a-1-1) of the formula (1), CH.sub.2 C(R.sup.1)COO--R.sup.2 (1) wherein R.sup.1 is a hydrogen atom or CH.sub.3 and R.sup.2 is an alkyl group, and/or an alkylene glycol (meth)acrylate monomer (a-1-2) of the formula (2) , CH.sub.2 .dbd.C(R.sup.1)COO(C.sub.n H.sub.2n O).sub.m R.sup.3(2) wherein R.sup.1 is a hydrogen atom or CH.sub.3, R.sup.3 is an alkyl group or a phenyl group, n is an integer of 1 to 3, and m is an integer of 3 to 25, and other polymerizable vinyl monomer (a-2), an average of molecular weights of all the monomers being 100 to 1,500, the liquid resin having a number average molecular weight of 10,000 to 200,000 and a viscosity of 1 to 10,000 poise (measured at 50.degree. C.), or a modified product of the above liquid resin, the curable liquid resin composition can form a film as a film-forming material or as a resin for an adhesive without using a solvent and give a cured film. |
| PATENT INVENTORS | This data is not available for free |
| PATENT ASSIGNEE | This data is not available for free |
| PATENT FILE DATE | 03.02.98 |
| PATENT CT FILE DATE | 02.06.97 |
| PATENT CT NUMBER | This data is not available for free |
| PATENT CT PUB NUMBER | This data is not available for free |
| PATENT CT PUB DATE | 11.12.97 |
| PATENT FOREIGN APPLICATION PRIORITY DATA | This data is not available for free |
| PATENT REFERENCES CITED | Patent Abstracts of Japan, 13(197) (P-868), abstract of JP 1-018142 (May 1989). |
| PATENT CLAIMS |
What is claimed is: 1. A curable liquid resin composition containing 100 parts by weight of the following (meth)acrylic liquid resin (A) and 1 to 1,000 parts by weight of a (meth)acrylic monomer (B) having an unsaturated double bond in its molecule and having a number average molecular weight of 1,000 or less, the (meth)acrylic liquid resin (A) being a liquid resin which is obtained by polymerizing monomers containing 10 to 100% by weight of an alkyl (meth)acrylate monomer (a-1-1) of the formula (1), CH.sub.2 .dbd.C(R.sup.1)COO--R.sup.2 ( 1) wherein R.sup.1 is a hydrogen atom or CH.sub.3 and R.sup.2 is an alkyl group having 4 to 22 carbon atoms, and/or an alkylene glycol (meth)acrylate monomer (a-1-2) of the formula (2) , CH.sub.2 .dbd.C(R.sup.1)COO (C.sub.n H.sub.2n O).sub.m R.sup.3( 2) wherein R.sup.1 is a hydrogen atom or CH.sub.3, R.sup.3 is an alkyl group having 1 to 5 carbon atoms or a phenyl group, n is an integer of 1 to 3, and m is an integer of 3 to 25, and 0 to 90% by weight of other polymerizable vinyl monomer (a-2), an average of molecular weights of all the monomers being 150 to 1,500, the liquid resin having a number average molecular weight of 10,000 to 200,000 and a viscosity of 1 to 10,000 poise (50.degree. C.), or the (meth)acrylic liquid resin (A) being a modified product of the above liquid resin. 2. A curable liquid resin composition according to claim 1, wherein the polymerizable vinyl monomer (a-2) is a vinyl monomer (a-2-1) having a functional group inert to radiation. 3. A curable liquid resin composition according to claim 2, wherein the vinyl monomer (a-2-1) is a component for forming the (meth)acrylic liquid resin (A) and contained therein in an amount of 1 to 50% by weight. 4. A curable liquid resin composition according to claim 2, wherein the vinyl monomer (a-2-1) is at least one monomer selected from the group consisting of alkyl (meth)acrylate whose alkyl group has 3 carbon atoms or less, an alkylene glycol (meth)acrylate monomer of the formula (3), CH.sub.2 .dbd.C(R.sup.1)COO(C.sub.n H.sub.2n O).sub.m R.sup.3( 3) wherein R.sup.1 is a hydrogen atom or CH.sub.3, R.sup.3 is an alkyl group having 1 to 5 carbon atoms or a phenyl group, n is an integer of 1 to 4, and m is an integer of 2 or less, styrene and vinyltoluene. 5. A curable liquid resin composition according to claim 2, wherein the vinyl monomer (a-2-1) is at least one monomer selected from the group consisting of a carboxyl-group-containing vinyl monomer, a hydroxyl-group-containing vinyl monomer and an amide-group-containing vinyl monomer. 6. A curable liquid resin composition according to claim 2, wherein the vinyl monomer (a-2-1) is a perfluoroalkyl-group-containing vinyl monomer. 7. A curable liquid resin composition according to claim 2, wherein the polymerizable vinyl monomer (a-2) is a functional vinyl monomer (a-2-2) having a functional group which is inert to radical polymerization but is active to radiation. 8. A curable liquid resin composition according to claim 7, wherein the functional vinyl monomer (a-2-2) is a component for forming the (meth)acrylic liquid resin (A) and contained therein in an amount of 1 to 60% by weight. 9. A curable liquid resin composition according to claim 7, wherein the functional vinyl monomer (a-2-2) is a vinyl monomer having an alicyclic epoxy group. 10. A curable liquid resin composition according to claim 7, wherein the functional vinyl monomer (a-2-2) is a siloxane-based vinyl monomer having a siloxane bond. 11. A curable liquid resin composition according to claim 7, wherein the polymerizable vinyl monomer (a-2) is a monomer prepared by further incorporating the vinyl monomer (a-2-1) to the functional vinyl monomer (a-2-2). 12. A curable liquid resin composition according to claim 11, wherein the vinyl monomer (a-2-1) is a component for forming the (meth)acrylic liquid resin (A) and contained therein in an amount of 0 to 79% by weight. 13. A curable liquid resin composition according to claim 1, wherein the modified product of the liquid resin is a reaction product from the (meth)acrylic liquid resin (A) having active hydrogen and an isocyanic ester compound (C) having an unsaturated double bond. 14. A curable liquid resin composition according to claim 13, wherein the isocyanic ester compound (C) is used in an amount of 0.1 to 100 mol per mole of the vinyl monomer (a-2-1). 15. A curable liquid resin composition according to claim 1, wherein the (meth)acrylic monomer (B) has a viscosity of 0.01 to 100 poise (measured at a temperature of 30.degree. C.). 16. A curable liquid resin composition according to claim 1, wherein the (meth)acrylic monomer (B) has a viscosity of 0.01 to 60 poise (measured at a temperature of 30.degree. C.). 17. A curable liquid resin composition according to claim 1, wherein the (meth)acrylic monomer (B) has a number average molecular weight of 1,000 or less. 18. A curable liquid resin composition according to claim 1, wherein R.sup.1 in the formula (1) is a hydrogen atom and/or R.sup.1 in the formula (2) is a hydrogen atom. 19. A curable liquid resin composition according to claim 1, wherein the alkyl (meth)acrylate monomer (a-1-1) of the formula (1) has an average molecular weight of at least 150. 20. A curable liquid resin composition according to claim 1, wherein the alkylene glycol (meth)acrylate monomer (a-1-2) of the formula (2) has an average molecular weight of at least 220. 21. A curable liquid resin composition according to claim 1, wherein the curable liquid resin composition has a viscosity of 0.01 to 1,000 poise (measured at a temperature of 50.degree. C.). 22. A curable liquid resin composition according to claim 1, wherein the curable liquid resin composition is radiation-curable. 23. A curable printing ink containing the curable liquid resin composition recited in claim 22. 24. A coating composition containing the curable liquid resin composition recited in claim 22. |
| PATENT PHOTOCOPY | Available on request |
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