| SUBJECT |
Alpha olefins are good reactive linear hydrocarbon chain source. However, many reactions tend to add the heteroatom at the second C, leading to a Me branch. Free radical chemistry is a convenient method to manufacture primary alkyl bromides, mercaptans & alkylphosphines Free radical additions between alpha olefins & compds contg S-H bond provide an opportunity to incorporate additional functional groups in the prodt. These prodts may have use in agricultural applications - RCH=CH2+HSCH2CO2Me = RCH2CH2SCH2CO2Me - RCH=CH2+HSCH2CH2OH = RCH2CH2SCH2CH2OH - RCH=CH2=H2S = RCH2CH2SH+(RCH2CH2)2S - RCH=CH2+NaHSO3 = RCH2CH2SO3Na+RCH(SO2Na)CH2SO3Na - RCH=CH2+ICHFCO2R' = RCH2CH2CHFCO2R' - RCH=CH2+ICF2CO2R' = RCHICH2CF2CO2R' - RCH=CH2+HBr = RCH2CH2Br - RCH=CH2+HPR'R'' = RCH2CH2PR'R'' |
| UPDATE | 09.00 |
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