PROPERTIES |
- Produce high MW polyethylene - Can tolerate contaminants - Work at low T & pressure - Do not require co-catalyst - Can polymerize olefins with functional groups |
TECHNOLOGY |
The author strategy was to start with the SHOP catalyst (developed by Shell), replacing the phos phorus-oxygen (PO)-based species with one based on the more sterically bulky salicylaldimine The author team synthesized a number of variants. They were able to produce polyethylene with MW > 250,000, narrow MW distribution, & very little branching. They were also able to copolymerize ethylene & olefins functionalized with polar groups such as -OH |
UPDATE | 01.00 |
AUTHOR | This data is not available for free |
LITERATURE REF. | This data is not available for free |
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