Main > POLYMERS > Poly(Olefin) > Catalyst > Metallocene > Isomerization > Catalytic Isomerization

Product USA. A

PATENT ASSIGNEE'S COUNTRY USA
UPDATE 10.99
PATENT ASSIGNEE This data is not available for free
PATENT CLAIMS Claim 1
A metallocene isomerization process which comprises heating an isomerization mixt formed from
- Meso form of bridged metallocene or mixt of meso & race
mic forms of bridged metallocene
- Group 1 &/or 2 metal halide isomerization catalyst
- Liquid organic isomerization medium
such that at least portion of meso form of metallocene is isomerized to racemic form
Claim 19
Process for prepn of chiral metallocene wherein
- Reaction prodt mixt is produced that comprises racemic &
meso forms of chiral metallocene of transition, lanthanide
or actinide metal in liquid organic reaction medium
- Group 1 or 2 metal halide isomerization catalyst is introdu
ced into mixt
- Mixt is heated
such that > 10% of meso form of metallocene is isomerized to racemic form
Claim 28
Process for converting meso chiral metallocene to racemic chiral metallocene, which process comprises contacting in a liquid organic medium
- Meso metallocene of a transition, lanthanide or actinide
metal in whatever chemical form & compn said meso meta
llocene exists when in said medium
- Group 1 or 2 metal halide isomerization catalyst in what
ever chemical form & compn said metal halide isomeriza
tion catalyst exists when in said medium
- Supplying sufficient heat energy to said medium
such that > 10% of meso metallocene is isomerized to racemic metallocene
PATENT PHOTOCOPY Available on request

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