| MARKETER'S COUNTRY |
CHI3 as source of iodine & NaOH as initiator of selective radical reaction The radical chain carrier is the triodomethyl radical which is generated in situ. The method is selective for tert. over sec. positions, & no primary C-H activation occurs |
| PREPARATION |
The first method for direct-free-radical iodination of aliphatic hydrocarbons using a multiphase system. The researchers converted straight-chain, branched, cyclic & cage alkanes into alkyl iodides by treat with CHI3 at RT in the presence of NaOH |
| UPDATE | 09.99 |
| AUTHOR | This data is not available for free |
| LITERATURE REF. | This data is not available for free |
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